Single and Double Nucleophilic-Addition to Coordinated PI-Hydrocarbons - Manganese-Mediated Functionalization of Arenes

A range of carbon-donor nucleophiles add to the arene ring in (arene)Mn(CO)2L+ cations to give neutral cyclohexadienyl complexes that liberate monofunctionalized arenes upon oxidative removal of the metal. Treatment of the cyclohexadienyl complexes with the nitrosonium salt NOPF6 affords cationic metal nitrosyl complexes that are attacked by a second nucleophile to give cis- and trans-difunctionalized 1,3-cyclohexadienes. When the metal center is chiral, this procedure provides a route to enantiomerically pure cyclohexadienes. 1. Introduction 2. Mechanism of Nucleophilic Addition 3. Single Nucleophilic Addition 4. Double Nucleophilic Addition 5. Conclusion

An Overview of the Rotational Behavior of Metal--Poor Stars

The present paper describes the behavior of the rotational velocity in metal--poor stars ([Fe/H]<-0.5 dex) in different evolutionary stages, based on Vsini values from the literature. Our sample is comprised of stars in the field and some Galactic globular clusters, including stars on the main sequence, the red giant branch (RGB), and the horizontal branch (HB). The metal--poor stars are, mainly, slow rotators, and their Vsini distribution along the HR diagram is quite homogeneous. Nevertheless, a few moderate to high values of Vsini are found in stars located on the main sequence and on the HB. We show that the overall distribution of Vsini values is basically independent of metallicity for the stars in our sample. In particular, the fast-rotating main sequence stars in our sample present similar rotation rates as their metal-rich counterparts, suggesting that some of them may actually be fairly young, in spite of their low metallicity, or else that at least some of them would be better classified as blue straggler stars. We do not find significant evidence of evolution in Vsini values as a function of position on the RGB; in particular, we do not confirm previous suggestions that stars close to the RGB tip rotate faster than their less evolved counterparts. While the presence of fast rotators among moderately cool blue HB stars has been suggested to be due to angular momentum transport from a stellar core that has retained significant angular momentum during its prior evolution, we find that any such transport mechanisms must likely operate very fast as the star arrives on the zero-age HB (ZAHB), since we do not find a link between evolution off the ZAHB and Vsini values. We present an extensive tabulation of all quantities discussed in this paper, including rotation velocities, temperatures, gravitieComment: 22 pages, 10 figure

The Second-Parameter Effect in Metal-Rich Globular Clusters

Recent Hubble Space Telescope observations have found that the horizontal branches (HB's) in the metal-rich globular clusters NGC 6388 and NGC 6441 slope upward with decreasing B-V. Such a slope is not predicted by canonical HB models and cannot be produced by either a greater cluster age or enhanced mass loss along the red-giant branch (RGB). The peculiar HB morphology in these clusters may provide an important clue for understanding the second-parameter effect. We have carried out extensive evolutionary calculations and numerical simulations in order to explore three non-canonical scenarios for explaining the sloped HB's in NGC 6388 and NGC 6441: i) A high cluster helium abundance scenario, where the HB evolution is characterized by long blue loops; ii) A rotation scenario, where internal rotation during the RGB phase increases the HB core mass; iii) A helium-mixing scenario, where deep mixing on the RGB enhances the envelope helium abundance. All three of these scenarios predict sloped HB's with anomalously bright RR Lyrae variables. We compare this prediction with the properties of the two known RR Lyrae variables in NGC 6388. Other possible observational tests are suggested.Comment: 12 pages, including three embedded figures. ApJ (Letters), in pres

The Dearth of UV-Bright Stars in M32: Implications for Stellar Evolution Theory

Using the Space Telescope Imaging Spectrograph on the Hubble Space Telescope, we have obtained deep far-ultraviolet images of the compact elliptical galaxy M32. When combined with earlier near-ultraviolet images of the same field, these data enable the construction of an ultraviolet color-magnitude diagram of the hot horizontal branch (HB) population and other hot stars in late phases of stellar evolution. We find few post-asymptotic giant branch (PAGB) stars in the galaxy, implying that these stars either cross the HR diagram more rapidly than expected, and/or that they spend a significant fraction of their time enshrouded in circumstellar material. The predicted luminosity gap between the hot HB and its AGB-Manque (AGBM) progeny is less pronounced than expected, especially when compared to evolutionary tracks with enhanced helium abundances, implying that the presence of hot HB stars in this metal-rich population is not due to (Delta Y)/(Delta Z) > 4. Only a small fraction (~2%) of the HB population is hot enough to produce significant UV emission, yet most of the UV emission in this galaxy comes from the hot HB and AGBM stars, implying that PAGB stars are not a significant source of UV emission even in those elliptical galaxies with a weak UV excess.Comment: Accepted for publication in The Astrophysical Journal. Latex, 18 pages, 18 black & white figures, in emulate-ApJ format. Figures 11 & 16 have been degraded due to size constraints; the high-quality version of the paper is at http://www.stsci.edu/~tbrown/research/m32fuv.pd

HST Snaphot Study of Variable Stars in Globular Clusters: Inner Region of NGC 6441

[Abridged] We present the results of a Hubble Space Telescope snapshot program to survey the inner region of the globular cluster NGC 6441 for its variable stars. A total of 57 variable stars was found including 38 RR Lyrae stars, 6 Population II Cepheids, and 12 long period variables. Of the RR Lyrae stars observed in this survey, 26 are pulsating in the fundamental mode with a mean period of 0.753d and 12 are first-overtone mode pulsators with a mean period of 0.365d. These values match up very well with those found in ground-based surveys. Combining all the available data for NGC 6441, we find mean periods of 0.759d and 0.375d for the RRab and RRc stars, respectively. We also find that the RR Lyrae in this survey are located in the same regions of a period-amplitude diagram as those found in ground-based surveys. Although NGC 6441 is a metal-rich globular cluster, its RR Lyrae more closely resemble those in Oosterhoff type II globular clusters. However, even compared to typical Oosterhoff type II systems, the mean period of its RRab stars is unusually long. We also derived I-band period-luminosity relations for the RR Lyrae stars. Of the six Population II Cepheids, five are of W Virginis type and one is a BL Herculis variable stars. This makes NGC 6441, along with NGC 6388, the most metal-rich globular cluster known to contain these types of variable stars. Another variable, V118, may also be a Population II Cepheid given its long period and its separation in magnitude from the RR Lyrae stars. We argue that there does not appear to be a change in the period-luminosity relation slope between the BL Herculis and W Virginis stars, but that a change of slope does occur when the RV Tauri stars are added to the period-luminosity relation.Comment: 28 pages, including 9 figures and 8 tables, emulateapj5/apjfonts style. Accepted by the Astronomical Journal. Approximate publication date September 2003. We recommend the interested reader to download the preprint with full-resolution figures, which can be found at http://www.astro.puc.cl/~mcatelan/Pritzl.zi

The Production of Sodium and Aluminum in Globular Cluster Red Giant Stars

We study the production of Na and Al around the hydrogen shell of two red-giant sequences of different metallicity in order to explain the abundance variations seen in globular cluster stars in a mixing scenario. Using detailed stellar models together with an extensive nuclear reaction network, we have calculated the distribution of the various isotopic abundances around the hydrogen shell at numerous points along the red-giant branch. These calculations allow for the variation in both temperature and density in the shell region as well as the timescale of the nuclear processing, as governed by the outward movement of the hydrogen shell. The reaction network uses updated rates over those of Caughlin \& Fowler (1988). We find evidence for the production of Na and Al occurring in the NeNa and MgAl cycles. In particular, Na is significantly enhanced throughout the region above the hydrogen shell. The use of the newer reaction rates causes a substantial increase in the production of $^{27}$Al above the hydrogen shell through heavy leakage from the NeNa cycle and should have an important effect on the predicted surface abundances. We also find that the nuclear processing is considerably more extensive at lower metallicities.Comment: 4 pages with 4 EPS figures embedded, accepted by ApJL March 28, 199

Variable Stars in the Unusual, Metal-Rich Globular Cluster NGC 6388

We have undertaken a search for variable stars in the metal-rich globular cluster NGC 6388 using time-series BV photometry. Twenty-eight new variables were found in this survey, increasing the total number of variables found near NGC 6388 to ~57. A significant number of the variables are RR Lyrae (~14), most of which are probable cluster members. The periods of the fundamental mode RR Lyrae are shown to be unusually long compared to metal-rich field stars. The existence of these long period RRab stars suggests that the horizontal branch of NGC 6388 is unusually bright. This implies that the metallicity-luminosity relationship for RR Lyrae stars is not universal if the RR Lyrae in NGC 6388 are indeed metal-rich. We consider the alternative possibility that the stars in NGC 6388 may span a range in [Fe/H]. Four candidate Population II Cepheids were also found. If they are members of the cluster, NGC 6388 would be the most metal-rich globular cluster to contain Population II Cepheids. The mean V magnitude of the RR Lyrae is found to be 16.85+/-0.05 resulting in a distance of 9.0 to 10.3 kpc, for a range of assumed values of for RR Lyrae. We determine the reddening of the cluster to be E(B-V)=0.40+/-0.03 mag, with differential reddening across the face of the cluster. We discuss the difficulty in determining the Oosterhoff classification of NGC 6388 and NGC 6441 due to the unusual nature of their RR Lyrae, and address evolutionary constraints on a recent suggestion that they are of Oosterhoff type II.Comment: 35 pages, 16 figures, emulateapj5/apjfonts style. Astronomical Journal, in press. We recommend the interested reader to download instead the preprint with full-resolution figures, which can be found at http://www.noao.edu/noao/staff/pritzl/clusters.htm

Red giant bound on the axion-electron coupling reexamined

If axions or other low-mass pseudoscalars couple to electrons (``fine structure constant'' $\alpha_a$) they are emitted from red giant stars by the Compton process $\gamma+e\to e+a$ and by bremsstrahlung $e+(Z,A)\to (Z,A)+e+a$. We construct a simple analytic expression for the energy-loss rate for all conditions relevant for a red giant and include axion losses in evolutionary calculations from the main sequence to the helium flash. We find that \alpha_a\lapprox0.5\mn(-26) or m_a\lapprox 9\,\meV/\cos^2\beta lest the red giant core at helium ignition exceed its standard mass by more than 0.025\,\MM_\odot, in conflict with observational evidence. Our bound is the most restrictive limit on $\alpha_a$, but it does not exclude the possibility that axion emission contributes significantly to the cooling of ZZ~Ceti stars such as G117--B15A for which the period decrease was recently measured.Comment: 11 pages, uuencoded and compressed postscript fil